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Campo DC | Valor | Lengua/Idioma |
---|---|---|
dc.contributor.other | GLORIA ALICIA DEL ANGEL MONTES | es_MX |
dc.contributor.other | JOSE GILBERTO TORRES TORRES | es_MX |
dc.contributor.other | CARLOS ANGELES CHAVEZ | es_MX |
dc.date.accessioned | 2018-07-11T20:52:38Z | - |
dc.date.available | 2018-07-11T20:52:38Z | - |
dc.date.issued | 2011 | - |
dc.identifier.uri | http://reini.utcv.edu.mx:80/handle/123456789/935 | - |
dc.description.abstract | "The Rh and Rh–Sn supported catalyst on -Al2O3 and -Al2O3–CeO2 (loading 1, 5 and 20 Ce wt%) were characterized by means of electron microscopy (TEM), temperature programmed reduction (TPR), Fourier transformed infrared of CO adsorption (FTIR-CO) and X-ray photoelectron spectroscopy (XPS). The catalysts were tested in the catalytic wet air oxidation of an aqueous solution of 227 ppm of TAME and 1 g/L of catalyst (120 ◦C and 10 bar of oxygen partial pressure). The rhodium monometallic catalysts showed an increase in the activity with the load of cerium oxide in the catalyst. The coexistence of Rh◦/Rh+ and Ce4+/Ce3+ redox couples facilitates the activation of TAME and hence the catalytic activity and selectivity to mineralization. The addition of Sn+ enhances the activity and selectivity; this is explained by assuming that Sn+ acts as Lewis acid sites trapping the TAME molecules for further oxidation on rhodium metal particles." | es_MX |
dc.language | spa | es_MX |
dc.publisher | Elsevier | es_MX |
dc.relation | I. Cuauhtémoc, G. Del Angel, G. Torres, C. Angeles-Chavez, J. Navarrete, J.M. Padilla, Enhancement of catalytic wet air oxidation of tert-amyl methyl ether by the addition of Sn and CeO2 to Rh/Al2O3 catalysts, Catalysis Today, Volume 166, Issue 1, 2011, Pages 180-187, ISSN 0920-5861, https://doi.org/10.1016/j.cattod.2010.11.100. | es_MX |
dc.rights | http://creativecommons.org/licenses/by/4.0 | es_MX |
dc.source | Catalysis Today, Volume 166, Issue 1 (ISSN: 0920-5861) | es_MX |
dc.subject | Nanotecnología | es_MX |
dc.title | Enhancement of catalytic wet air oxidation of tert-amyl methyl ether by the addition of Sn and CeO2 to Rh/Al2O3 catalysts | es_MX |
dc.type | info:eu-repo/semantics/article | es_MX |
dc.audience | generalPublic | es_MX |
dc.rights.access | info:eu-repo/semantics/openAccess | es_MX |
dc.author | IGNACIO CUAUHTEMOC LOPEZ*info:eu-repo/dai/mx/cvu/*39617 | es_MX |
dc.author | CARLOS ANGELES CHAVEZ*info:eu-repo/dai/mx/cvu/*20404 | es_MX |
dc.author | JOSE GILBERTO TORRES TORRES*info:eu-repo/dai/mx/cvu/*121293 | es_MX |
dc.author | GLORIA ALICIA DEL ANGEL MONTES*info:eu-repo/dai/mx/cvu/*3780 | es_MX |
dc.area | info:eu-repo/classification/cti/7 | es_MX |
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Artículo_Enhancement of catalytic wet air oxidation of tert-amyl methyl ether by the addition of sn.pdf | 1.17 MB | Adobe PDF | Visualizar/Abrir |
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